Titanium Dioxide Food Grade - High Purity for Food and Beverage Applications
Introduction
Titanium dioxide (TiO₂) is a naturally occurring mineral widely used as a white pigment in various industries, including food and beverages. Its exceptional brightness, opacity, and stability make it a popular choice for enhancing the visual appeal of products. Food-grade titanium dioxide, designated as E171 in Europe and compliant with FDA 21 CFR 73.575 in the United States, is specifically refined to meet stringent safety and purity standards for human consumption.
In recent years, the safety of titanium dioxide in food has been debated, with some regions imposing restrictions. However, high-purity, food-grade TiO₂ remains approved in many countries for use in confectionery, dairy products, sauces, and beverages—where it serves as a whitening and opacifying agent.
This article explores the properties, applications, safety considerations, and regulatory status of food-grade titanium dioxide, providing a comprehensive overview for manufacturers and suppliers in the food industry.
Properties of Food-Grade Titanium Dioxide
Food-grade titanium dioxide is distinguished by its:
1. Exceptional Whiteness and Opacity
TiO₂ has one of the highest refractive indices among white pigments, meaning it effectively scatters light to produce a bright, opaque appearance. This property is crucial for applications where a clean, uniform white color is desired, such as in icings, chewing gum, and dairy alternatives.
2. High Purity (≥99%)
Unlike industrial-grade TiO₂, food-grade titanium dioxide undergoes rigorous purification to remove heavy metals and other impurities. This ensures compliance with global food safety regulations.
3. Ultra-Fine Particle Size
Food-grade TiO₂ is milled to a fine particle size (typically between 200-300 nm), which enhances dispersion in liquids and prevents grittiness in final products.
4. Chemical Stability
TiO₂ is inert, non-reactive, and resistant to heat, light, and pH variations, making it suitable for a wide range of food processing conditions.
5. Low Solubility
It does not dissolve in water or organic solvents, ensuring that it remains suspended in products without altering taste or texture.
Applications in the Food and Beverage Industry
Due to its unique properties, food-grade titanium dioxide is used in numerous applications:
1. Confectionery and Bakery Products
Chewing gum, candies, and chocolates – Provides a smooth, bright white coating or filling.
Icing and decorative toppings – Enhances whiteness and improves visual appeal.
Marshmallows and meringues – Creates a pure white appearance.
2. Dairy and Dairy Alternatives
Cheeses, yogurts, and creamers – Improves opacity and brightness, especially in low-fat or plant-based alternatives.
Whipped toppings – Ensures a consistent white color.
3. Sauces, Dressings, and Condiments
Mayonnaise and salad dressings – Used to achieve a creamy, opaque look.
White sauces and dips – Enhances visual consistency.
4. Beverages
Milk-based drinks and protein shakes – Improves opacity for a richer appearance.
Flavored waters and powdered drink mixes – Used in minimal quantities for visual enhancement.
5. Pharmaceutical and Supplement Coatings
Tablet coatings and capsules – Provides a smooth, white finish for easy identification.
Safety and Regulatory Considerations
The use of titanium dioxide in food has faced regulatory scrutiny, leading to varying approvals worldwide:
1. European Union (EU) Ban on E171
In 2022, the European Food Safety Authority (EFSA) declared titanium dioxide (E171) no longer considered safe as a food additive due to concerns over nanoparticle accumulation. As a result, the EU banned its use in food products, though it remains permitted in medicines and supplements.
2. U.S. FDA Approval
The U.S. Food and Drug Administration (FDA) continues to approve titanium dioxide (21 CFR 73.575) as a safe food colorant within specified limits.
3. Other Regions
Canada, Australia, and Japan permit its use with restrictions.
Some manufacturers are voluntarily phasing it out due to consumer demand for cleaner labels.
4. Alternatives to Titanium Dioxide
Due to regulatory shifts, food producers are exploring alternatives such as:
Calcium carbonate
Starch-based opacifiers
Rice flour
However, none match TiO₂’s brightness and performance, creating formulation challenges.
Appearance | White to slightly yellow, powder |
Density | 4.23 g/cm3 |
Melting Point | 1843 °C |
Boiling Point | 2500-3000 °C |
Flash Point | 2500-3000°C |
Refractive Index | 2.61 |
Water Solubility | Insoluble |
Vapor Pressure | 0 mmHg (approx) |
Flammability characteristics | Noncombustible Solid |
Odor | Odorless |
Taste | TASTELESS |
PH | SUSPENSION IN WATER (1 IN 10) IS NEUTRAL TO LITMUS |
Experimental Properties | GRAVIMETRIC FACTOR: 0.33279|RUTILE: X-RAY CRYSTALLOGRAPHIC DATA: CRYSTAL SYSTEM: TETRAGONAL; SPACE GROUP: P4/MNM(136); 2 G FORMULA WT/UNIT CELL; X-RAY CRYSTALLOGRAPHIC DATA: AO= 4.5937 + OR - 0.0005; CO= 2.9618 + OR - 0.0010|ANATASE: X-RAY CRYSTALLOGRAPHIC DATA: CRYSTAL SYSTEM: TETRAGONAL; SPACE GROUP: I41/AMD(141); 4 G FORMULA WT/UNIT CELL X-RAY CRYSTALLOGRAPHIC DATA: AO= 3.785 + OR - 0.002; CO= 9.514 + OR - 0.006|BROOKITE: X-RAY CRYSTALLOGRAPHIC DATA: CRYSTAL SYSTEM: ORTHORHOMBIC; SPACE GROUP: PCAB (61); 8 G FORMULA WT/UNIT CELL X-RAY CRYSTALLOGRAPHIC DATA: AO= 5.456 + OR - 0.002; BO= 9.182 + OR - 0.005; CO= 5.143 + OR - 0.003|For more Other Experimental Properties (Complete) data for TITANIUM DIOXIDE (6 total), please visit the HSDB record page.|White, tetrahedral crystals; MP: 1843 °C; BBP: approximately 3000 °C; density: 4.17 g/cu cm. Insoluble in water, dilute acid; soluble in concentrated acid /Titanium(IV)oxide (Rutile)/ |
Air and Water Reactions | Insoluble in water. |
Reactive Group | Non-Redox-Active Inorganic Compounds |
Reactivity Profile | TITANIUM DIOXIDE is incompatible with strong oxidizers and strong acids. Violent or incandescent reactions may occur with metals (e.g. aluminum, calcium, magnesium, potassium, sodium, zinc and lithium). (NTP, 1992). |
Flammable Limits | Noncombustible Solid |



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